From Wikipedia -
Since 1960, the supply voltage in Great Britain in domestic premises has been 240 V AC (rms) at 50 Hz while in Northern Ireland it was 220 V. In 1988, a Europe-wide agreement was reached to change the various national voltages, which ranged at the time from 220 V to 240 V, to a common European standard of 230 V (CENELEC Harmonization Document HD 472 S1:1988).
As a result, the standard nominal supply voltage in domestic single-phase 50 Hz installations in the UK has been 230 V AC (rms) since 1 January 1995 (Electricity Supply Regulations, SI 1994, No. 3021). However, as an interim measure, electricity suppliers can work with an asymmetric voltage tolerance of 230 V +10%/−6% (216.2 V to 253 V). This was supposed to be widened to 230 V ±10% (207 V to 253 V), but the time of this change has been put back repeatedly and currently sits in 2008 (BS 7697). The old standard was 240 V ±6% (225.6 V to 254.4 V), which is mostly contained within the new range, and so in practice suppliers have had no reason to actually change voltages. In Europe the range was 220V ±10%.
The continued deviation in the UK from the harmonised European voltage has been criticised in particular by light bulb manufacturers, who require tighter voltage tolerances to optimise the operating temperature and lifetime of their products, and who currently have to continue producing separate 230 V and 240 V versions.