Yes, please do document your experience! For what it's worth, the photo that B&O uses on their website shows a stereo pair facing directly front: https://www.bang-olufsen.com/en/us/speakers/beosound-balance-stereo-set , page down.
The argument for toeing them in is that tweeter directivity will give you a more even frequency response, and you'll also have improved left/right localization/soundstage. But the front side has 2 full-range drivers and the tweeter, and those left/right full-rangers are already slightly toed out -- they appear to follow the radius of the cylinder, not be inset flat -- which makes perfect sense given that the speaker was intended to be a stereo source from a single enclosure. Therefore... ... ...
The argument against toeing them in is that with the rear full-rangers enlarging the sound field, because the speaker was specifically designed for placement up against a wall, a whole lot of incoherent-no-matter-how-they-adjust-it sound is floating around. So whether soundstage is improved because toe-in moves the side-wall reflection just doesn't matter. I would bet that any Active Room Compensation algorithm will work best with a known perpendicular surface, because in-phase and out-of-phase will vary by frequency, so don't left and right rear drivers *already* have different EQ curves & delays? Complicate that with a stereo pair interfering with each other... yikes! Do they tell you to re-run the compensation setup with both speakers active? (Knowing nothing, I bet not!) Maybe some engineer would also auto-adjust the "inner 2" drivers of each speaker down in volume when doing stereo pairing, to reduce the "room filling" effect which becomes less desirable when left/right are trying to create a stereo image?
Worse, the app's left/front/right steering control must use the opposing set of drivers to cancel out sound rather than expand the sound field, which will be really weird in stereo! This product definitely needs a Technical Sound Guide to tell us what's actually going on, but product manuals are not B&O's forte, both by design/execution & (I believe) by intent. Where does "trade secret" end and "hocus pocus" begin? Definitely looking forward to your impressions and very much hope you try it both ways yourself.